This book presents a comprehensive review of recent developments in vanadium-based nanomaterials for next-generation electrochemical energy storage. The basic electrochemical energy storage and conversion equipment are elaborated, and the vanadium-based nanomaterials of the synthesis approaches, characterizations, electrochemical storage mechanisms, and performance optimization tactics are discussed. Examples are taken from various chemical energy storage devices to expound the functions of advanced vanadium-based nanomaterials for specific applications. Finally, various challenges and perspectives on vanadium-based nanomaterial development as an emerging energy storage solution are considered.